Experimental and theoretical insights into the formation of weak hydrogen bonds and H⋯H bonding interactions in the solid-state structure of two eucalyptol derivatives-Reference-Cited by-同舟云学术

Experimental and theoretical insights into the formation of weak hydrogen bonds and H⋯H bonding interactions in the solid-state structure of two eucalyptol derivatives

Published:2022 Issue:12 Volume:46 Page:5690-5704
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Galvez Carolina E.¹,Piro Oscar E.²,Echeverría Gustavo A.²,Robles Norma Lis³,Lezama José O. G.⁴,Sankaran Sankaran Venkatachalam⁵,Thamotharan Subbiah⁵,Villecco Margarita B.¹,Loandos María del H.¹,Gil Diego M.⁴^ORCID

Affiliation:

1. Cátedra de Química Orgánica II, Instituto de Química Orgánica, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471, T4000INI, San Miguel de Tucumán, Argentina

2. Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata e IFLP (CONICET, CCT-La Plata), C. C. 67, 1900, La Plata, Argentina

3. INQUINOA (CONICET – UNT), Facultad de Ciencias Exactas y Tecnología, Universidad Nacional de Tucumán. Av. Independencia 1800, CP 4000, San Miguel de Tucumán, Argentina

4. INBIOFAL (CONICET – UNT), Instituto de Química Orgánica, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471, T4000INI, San Miguel de Tucumán, Argentina

5. Biomolecular Crystallography Laboratory, Department of Bioinformatics, School of Chemical and Biotechnology, SASTRA Deemed University, Thanjavur 613 401, India

Abstract

We report the synthesis and X-ray solid-state structure of two eucalyptol derivatives. Both compounds form self-assembled dimers establishing C–H⋯O hydrogen bonds and H⋯H bonding interactions.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Universidad Nacional de Tucumán

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00428C

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1. Herbicidal Activity of Cineole Derivatives

2. Mutagenicity testing of (±)-camphor, 1,8-cineole, citral, citronellal, (−)-menthol and terpineol with the Salmonella/microsome assay