Bis-tropolonate complexes of tungsten: scaffolds for selective side-on binding of nitriles, imines and ketones-Reference-Cited by-同舟云学术

Bis-tropolonate complexes of tungsten: scaffolds for selective side-on binding of nitriles, imines and ketones

Published:2014 Issue:23 Volume:43 Page:8738-8748
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Becica Joseph¹²³,Jackson Andrew B.¹²³,Dougherty William G.⁴⁵⁶,Kassel W. Scott⁴⁵⁶,West Nathan M.¹²³

Affiliation:

1. Department of Chemistry & Biochemistry

2. University of the Sciences

3. Philadelphia, USA

4. Department of Chemistry

5. Villanova University

6. Villanova, USA

Abstract

The bis-tropolonate tungsten(ii) tricarbonyl compound, (trop)₂W(CO)₃ will preferentially bind nitriles, imines, and aldehydes in a side-on fashion. Crystallographic analysis of the imine adduct supports the postulation of 4-electron donation from the imine.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00734D

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