A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media-Reference-Cited by-同舟云学术

A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Published:2017 Issue:78 Volume:53 Page:10816-10819
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Surbella Robert G.¹²³⁴⁵^ORCID,Ducati Lucas C.⁶⁷⁸⁹^ORCID,Pellegrini Kristi L.¹⁰¹¹¹²⁵,McNamara Bruce K.¹⁰¹¹¹²⁵,Autschbach Jochen¹¹³¹⁴¹⁵¹⁶^ORCID,Schwantes Jon M.⁶⁷⁸⁹,Cahill Christopher L.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. The George Washington University

3. 800 22nd Street

4. NW

5. USA

6. Department of Fundamental Chemistry Institute of Chemistry

7. University of São Paulo

8. Av. Prof. Lineu Prestes 748

9. Brazil

10. Pacific Northwest National Laboratory

11. 902 Battelle Boulevard

12. Richland

13. University at Buffalo

14. State University of New York

15. 312 Natural Sciences Complex

16. Buffalo

Abstract

A novel hydrated Pu(iii) chloride, (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·Cl·2H₂O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Office of Science

Science and Technology Directorate

Fundação de Amparo à Pesquisa do Estado de São Paulo

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC05988D

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