Force-modulated reductive elimination from platinum(ii) diaryl complexes

Author:

Yu Yichen1,Wang Chenxu2,Wang Liqi1,Sun Cai-Li2,Boulatov Roman2ORCID,Widenhoefer Ross A.1,Craig Stephen L.1ORCID

Affiliation:

1. Department of Chemistry, Duke University, Durham, North Carolina 27708, USA

2. Department of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK

Abstract

The influence of mechanical force on the rates of model reductive elimination reactions depends on the structure of the force-transducing ligand and provides a measure of geometry changes upon reaching the transition state.

Funder

American Chemical Society Petroleum Research Fund

National Science Foundation

Engineering and Physical Sciences Research Council

U.S. Department of Energy

Office of Science

Basic Energy Sciences

San Diego Supercomputer Center

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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