Unequal coordination environment in complexes of the type [Au2Ag2(R)4(L)2]n. An immiscible solvent mixture as a key point in the control of ligand replacement-Reference-Cited by-同舟云学术

Unequal coordination environment in complexes of the type [Au2Ag2(R)4(L)2]n. An immiscible solvent mixture as a key point in the control of ligand replacement

Published:2018 Issue:10 Volume:47 Page:3231-3238
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

López-de-Luzuriaga José M.¹²³⁴⁵^ORCID,Monge Miguel¹²³⁴⁵^ORCID,Olmos M. Elena¹²³⁴⁵^ORCID,Quintana Javier¹²³⁴⁵^ORCID,Rodríguez-Castillo María¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química

2. Universidad de La Rioja

3. Centro de Investigación en Síntesis Química (CISQ)

4. Complejo Científico-Tecnológico

5. 26004-Logroño

Abstract

A new photoluminescent heterometallic polymer [Au₆Ag₆(C₆Cl₂F₃)₁₂(μ₂-pym)₂(NCMe)₆]_n (2) with three different coordination environments has been synthesised.

Funder

Secretaría de Estado de Investigación Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00024G

Reference40 articles.

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2. Cyclic Triradicals Composed of Iminonitroxide-Gold(I) with Intramolecular Ferromagnetic Interactions

3. Metallophilicity-Driven Dynamic Aggregation of a Phosphorescent Gold(I)–Silver(I) Cluster Prepared by Solution-Based and Mechanochemical Approaches

4. Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(μ-C2,N3-bzim)]3)2}BF4·CH2Cl2, {Tl([Au(μ-C2,N3-bzim)]3)2}PF6·0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(μ-C(OEt)═NC6H4CH3)]3)2}PF6·THF, with MAu6 (M = Ag+, Tl+) Cluster Cores

5. Triple-Decker Au3-Ag-Au3-Ag-Au3Ion Cluster Enclosed in a Self-Assembled Cage

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