A polyester–polystyrene hybrid connected by dynamic covalent bonds prepared via radical polymerization of styrene in a “RAFT gel”-Reference-Cited by-同舟云学术

A polyester–polystyrene hybrid connected by dynamic covalent bonds prepared via radical polymerization of styrene in a “RAFT gel”

Published:2014 Issue:11 Volume:5 Page:3689-3696
ISSN:1759-9954
Container-title:Polym. Chem.
language:en
Short-container-title:Polym. Chem.

Author:

Yoshimura Daiki¹²³⁴,Yamada Shinji¹²³⁴,Takasu Akinori¹²³⁴

Affiliation:

1. Department of Frontier Materials

2. Graduate School of Engineering

3. Nagoya Institute of Technology

4. Nagoya 466-8555, Japan

Abstract

We cross-linked the polyester chains with 1,1-thiocarbonyldiimidazole to form a reversible addition–fragmentation chain-transfer (RAFT) gel, in which the trithiocarbonate moiety acted as a cross-linker. The “RAFT gel” was then swollen in vinyl monomers and styrene was radically polymerized within the gel, in which the polyester and polystyrene segments were miscible at the segment level.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2014/PY/C4PY00052H

Reference39 articles.

1. Biodegradable polymers

2. V. V. Korshak and S. V.Vinogradova , Polyester , Pergamon Press , New York , 1965

3. Synthesis of Aliphatic Polyesters by Direct Polyesterification of Dicarboxylic Acids with Diols under Mild Conditions Catalyzed by Reusable Rare-Earth Triflate

4. Environmentally Benign Polyester Synthesis by Room Temperature Direct Polycondensation of Dicarboxylic Acid and Diol

5. Polycondensation of Dicarboxylic Acids and Diols in Water Catalyzed by Surfactant-Combined Catalysts and Successive Chain Extension

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis of L‐ Malic Acid Based Poly(ester‐thioether)s via Thiol‐Ene Click Polymerization and Their Biodegradability;ChemistrySelect;2021-09-17

2. Grafting of Poly(2‐Oxazoline) Side Chains from Polyester Containing Oxazoline Units and Their Blends with Water Soluble Vinyl Polymers;Macromolecular Chemistry and Physics;2020-12-14

3. Experimental and Theoretical Investigation of Intrinsic Pyridine Isomer Effects on Physical Property Tuning of Metallo Supramolecular Polymers Bearing Multiple Pyridine Ligands;ACS Applied Polymer Materials;2020-05-18

4. Preparation of All Polyester‐Based Semi‐IPN Elastomers Containing Self‐Associative or Non‐Associative Guest Chains via Post‐Blending Cross‐Linking;Macromolecular Materials and Engineering;2019-05-16

5. Simple Strategy for Dual Control of Crystallization and Thermal Property on Polyesters by Dispersing Metal Salts Via Multiple Coordination Bonds;Macromolecular Chemistry and Physics;2018-07-08