A five-fold interpenetrated metal–organic framework showing a large variation in thermal expansion behaviour owing to dramatic structural transformation upon dehydration

A five-fold interpenetrated metal–organic framework showing a large variation in thermal expansion behaviour owing to dramatic structural transformation upon dehydration–rehydration

Published:2017 Issue:5 Volume:53 Page:861-864
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Aggarwal Himanshu¹²³⁴,Das Raj Kumar¹²³⁴,Engel Emile R.¹²³⁴,Barbour Leonard J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Polymer Science

2. University of Stellenbosch

3. Stellenbosch

4. South Africa

Abstract

A five-fold interpenetrated MOF has the highest uniaxial negative thermal expansion coefficient reported for any interpenetrated MOF to date. Upon dehydration, the framework shows considerable change in the magnitudes of the thermal expansion coefficients.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC07995D

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