Covalent organic framework-based Li–S batteries: functional separators promoting Li+ transport and polysulfide trapping

Author:

Gullace Sara1ORCID,Abruzzese Matteo2,Cusin Luca1,Saleh Gabriele3,Thorat Sanjay B.2,Gamberini Agnese2,Bellani Sebastiano2,Ciesielski Artur1ORCID,Bonaccorso Francesco23,Samorì Paolo1ORCID

Affiliation:

1. Institut de Science et d’Ingénierie Supramoléculaires, Université de Strasbourg, CNRS, 8 allée Gaspard Monge, 67000, Strasbourg, France

2. BeDimensional S.p.A., Via Lungotorrente Secca, 30R, 16163 Genova, Italy

3. Istituto Italiano di Tecnologia, Via Morego, 30, 16163 Genova, Italy

Abstract

Li–S batteries (LSBs) comprising two Kagome imine COFs as modifiers for Celgard separators are fabricated. The work highlights the cooperative effect of polysulfide trapping, Li+ sieving and electrocatalytic properties for high-performance LSBs.

Funder

H2020 Marie Skłodowska-Curie Actions

Horizon 2020 Framework Programme

HORIZON EUROPE Framework Programme

Institut Universitaire de France

Publisher

Royal Society of Chemistry (RSC)

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