Photocrystallography of [Ru(bpy)2(dmso)2]2+ reveals an O-bonded metastable state-Reference-Cited by-同舟云学术

Photocrystallography of [Ru(bpy)₂(dmso)₂]²⁺ reveals an O-bonded metastable state

Published:2023 Issue:26 Volume:14 Page:7279-7284
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Marr Zoe Y.¹^ORCID,Thapa Magar Rajani²^ORCID,Fournier Bertrand³⁴,Benedict Jason B.¹^ORCID,Rack Jeffrey J.²^ORCID

Affiliation:

1. Department of Chemistry, The State University of New York at Buffalo, Buffalo, NY 14260, USA

2. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131-001, USA

3. Institut Galien Paris-Saclay, CNRS UMR 8612, Université Paris-Saclay, 91400 Orsay, France

4. Université Paris-Saclay, CentraleSupélec, CNRS, Laboratoire SPMS, 91190 Gif-sur-Yvette, France

Abstract

We report the first observation of the phototriggered isomerization of dmso ligands on a bis sulfoxide complex, [Ru(bpy)2(dmso)2], in the crystalline solid state.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01526B

Reference51 articles.

1. Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes

2. Photosalient Behavior of Photoreactive Crystals

3. Mechanically Responsive Molecular Crystals

4. The Rise of the Dynamic Crystals

5. Bridging photochemistry and photomechanics with NMR crystallography: the molecular basis for the macroscopic expansion of an anthracene ester nanorod

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