Reactivity of quasi-free electrons toward N3− and its impact on H2 formation mechanism in water radiolysis-Reference-Cited by-同舟云学术

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Reactivity of quasi-free electrons toward N₃⁻ and its impact on H₂ formation mechanism in water radiolysis

Published:2024 Issue:15 Volume:26 Page:11604-11610
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Dobrovolskii Denis¹^ORCID,Denisov Sergey A.¹^ORCID,Sims Howard E.²,Mostafavi Mehran¹^ORCID

Affiliation:

1. Institut de Chimie Physique, Université Paris-Saclay, CNRS, Bâtiment 349, Orsay, 91405, France

2. Central Laboratory, National Nuclear Laboratory, Sellafield, Seascale CA20 1PG, UK

Abstract

Picosecond pulse radiolysis measurements were employed to assess the effectiveness of N3− in scavenging quasi-free electrons in aqueous solutions.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00157E

Reference47 articles.

1. G.Buxton , The Radiation Chemistry of Liquid Water , Charged Particle and Photon Interactions with Matter , CRC Press , 2003

2. J. V.Belloni , M.Mostafavi , T.Douki and M.Spotheim-Maurizot , Radiation chemistry from basics to applications in material and life sciences , EDP Sciences , 2008

3. Applications of the spur diffusion model to the radiation chemistry of aqueous solutions

4. Dependence of Molecular Hydrogen Formation in Water on Scavengers of the Precursor to the Hydrated Electron

5. The nature of the precursors of radiolytic molecular hydrogen in water, and the mechanism of positronium formation in liquids

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