Comparing the reactivity of an oxoiron(<scp>iv</scp>) cation radical and its oxoiron(<scp>v</scp>) tautomer towards C

Comparing the reactivity of an oxoiron(iv) cation radical and its oxoiron(v) tautomer towards C–H bonds

Published:2023 Issue:19 Volume:59 Page:2755-2758
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jana Sandipan¹^ORCID,Pattanayak Santanu¹,Das Soumadip¹,Ghosh Munmun²,Velasco Lucia³,Moonshiram Dooshaye³^ORCID,Sen Gupta Sayam¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India

2. Department of Chemistry, Ashoka University, Rajiv Gandhi Education City, Sonepat, Haryana 131029, India

3. Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain

Abstract

An oxoiron(iv) cation radical is generated upon two-electron oxidation of an iron(iii) complex bearing an electron-rich methoxy substituted bTAML framework and characterized via multiple spectroscopic techniques and density functional theory (DFT).

Funder

Science and Engineering Research Board

University Grants Commission

Council of Scientific and Industrial Research, India

Ministerio de Sanidad, Política Social e Igualdad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC07005G

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