Dinuclear manganese(iii) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectroscopic and computation study-Reference-Cited by-同舟云学术

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Dinuclear manganese(iii) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectroscopic and computation study

Published:2019 Issue:18 Volume:48 Page:5909-5922
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shova Sergiu¹²³⁴,Vlad Angelica¹²³⁴,Cazacu Maria¹²³⁴^ORCID,Krzystek J.⁵⁶⁷⁸^ORCID,Ozarowski Andrew⁵⁶⁷⁸^ORCID,Malček Michal⁹¹⁰¹¹¹²,Bucinsky Lukas⁹¹⁰¹¹¹²,Rapta Peter⁹¹⁰¹¹¹²,Cano Joan¹³¹⁴¹⁵¹⁶^ORCID,Telser Joshua¹⁷¹⁸¹⁹²⁰⁸^ORCID,Arion Vladimir B.²¹²²²³^ORCID

Affiliation:

1. Inorganic Polymers Department

2. “Petru Poni” Institute of Macromolecular Chemistry

3. Iasi 700487

4. Romania

5. National High Magnetic Field Laboratory

6. Florida State University

7. Tallahassee

8. USA

9. Institute of Physical Chemistry and Chemical Physics

10. Slovak University of Technology in Bratislava

11. 81237 Bratislava

12. Slovak Republic

13. Institut de Ciència Molecular

14. Universitat de València

15. 46980 Paterna

16. Spain

17. Department of Biological

18. Physical and Health Sciences

19. Roosevelt University

20. Chicago

21. Institute of Inorganic Chemistry of the University of Vienna

22. A1090 Vienna

23. Austria

Abstract

High-resolution HFEPR indicates weak exchange interactions between Mn^III ions in agreement with DFT calculations.

Funder

Consiliul National al Cercetarii Stiintifice

Österreichische Agentur für Internationale Mobilität und Kooperation in Bildung, Wissenschaft und Forschung

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Ministerstvo školstva, vedy, výskumu a športu Slovenskej republiky

National Science Foundation

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04596H

Reference101 articles.

1. Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases

2. Crystal Structure of Manganese Catalase from Lactobacillus plantarum

3. Three-dimensional structure of the enzyme dimanganese catalase from Thermus Thermophilus at 1 Å resolution

4. An Active Dimanganese(III)−Tyrosyl Radical Cofactor in Escherichia coli Class Ib Ribonucleotide Reductase

5. A Tyrosyl−Dimanganese Coupled Spin System is the Native Metalloradical Cofactor of the R2F Subunit of the Ribonucleotide Reductase of Corynebacterium ammoniagenes

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