A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations-Reference-Cited by-同舟云学术

A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations

Published:2020 Issue:10 Volume:7 Page:2072-2079
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Luo Xi-Ming¹²³⁴⁵,Li Ning-Fang¹²³⁴⁵,Lin Qing-Fang¹²³⁴⁵,Cao Jia-Peng¹²³⁴⁵,Yuan Peng¹²³⁴⁵,Xu Yan¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemical Engineering

2. State Key Laboratory of Materials-Oriented Chemical Engineering

3. Nanjing Tech University

4. Nanjing 210009

5. P. R. China

Abstract

Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln₆₀. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/D0QI00226G

Reference46 articles.

1. Anion-Dependent Assembly of 3d–4f Heterometallic Clusters Ln5Cr2 and Ln8Cr4

2. Wheel-like Ln18 Cluster Organic Frameworks for Magnetic Refrigeration and Conversion of CO2

3. Ultrastrong Alkali-Resisting Lanthanide-Zeolites Assembled by [Ln60] Nanocages

4. Four 3d–4f heterometallic Ln45M7 clusters protected by mixed ligands

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