Spontaneous mirror symmetry breaking: an entropy production survey of the racemate instability and the emergence of stable scalemic stationary states-Reference-Cited by-同舟云学术

Spontaneous mirror symmetry breaking: an entropy production survey of the racemate instability and the emergence of stable scalemic stationary states

Published:2020 Issue:25 Volume:22 Page:14013-14025
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ribó Josep M.¹²³⁴⁵^ORCID,Hochberg David⁶⁷⁸⁴^ORCID

Affiliation:

1. Department of Organic Chemistry

2. University of Barcelona

3. E-08028 Barcelona

4. Spain

5. Institute of Cosmos Science (IEEC-UB)

6. Department of Molecular Evolution

7. Centro de Astrobiology (CSIC-INTA)

8. E-28850 Torrejón de Ardoz

Abstract

Stability of non-equilibrium stationary states and spontaneous mirror symmetry breaking, provoked by the destabilization of the racemic thermodynamic branch, is studied for enantioselective autocatalysis in an open flow system, and for a continuous range n of autocatalytic orders.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02280B

Reference61 articles.

1. Homogeneous Chiral Autocatalysis: A Simple, Purely Stochastic Kinetic Model

2. Stochastic Kinetic Models of Chiral Autocatalysis: A General Tool for the Quantitative Interpretation of Total Asymmetric Synthesis

3. Chiral Autocatalysis, Spontaneous Symmetry Breaking, and Stochastic Behavior