Stereoselective synthesis of 1,3- and 1,4-dicarbonyl-alkenes from cyclopropenes in a catalytic zinc system-Reference-Cited by-同舟云学术

Stereoselective synthesis of 1,3- and 1,4-dicarbonyl-alkenes from cyclopropenes in a catalytic zinc system

Published:2023 Issue:19 Volume:10 Page:4887-4894
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Han Jiabin¹,Liu Yu¹,Yang Xiaoyan²,Zhang Xuheng¹,Zhu Yuanhao¹,Zhao Min²,Hao Gefei²^ORCID,Jiang Yaojia¹²^ORCID

Affiliation:

1. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

2. Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education, Guizhou University, Huaxi District, Guiyang 550025, China

Abstract

This work describes a dual catalytic system for selective synthesis of α-allyl-1,3-ketoaldehydes and α-vinyl-1,4-ketoaldehydes through cascade reactions of hydroxyl substituted aromatic enaminones with cyclopropenes under zinc promoted conditions.

Funder

Guizhou University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00559C

Reference75 articles.

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2. New Approaches to the Synthesis of Metal Carbenes

3. Construction of heterocyclic rings from cyclopropenes

4. Intramolecular Cyclopropanation and C–H Insertion Reactions with Metal Carbenoids Generated from Cyclopropenes

5. Recent developments of cyclopropene chemistry

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