Exceptional proton affinities of push–pull nitriles substituted by the guanidino and phosphazeno groups-Reference-Cited by-同舟云学术

Exceptional proton affinities of push–pull nitriles substituted by the guanidino and phosphazeno groups

Published:2015 Issue:32 Volume:5 Page:25513-25517
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Raczyńska Ewa D.¹²³⁴,Gal Jean-François⁵⁶⁷⁸,Maria Pierre-Charles⁵⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. Warsaw University of Life Sciences (SGGW)

3. 02-776 Warszawa

4. Poland

5. Institut de Chimie de Nice (ICN) – UMR CNRS 7272

6. University Nice Sophia Antipolis

7. 06108 Nice Cedex 2

8. France

Abstract

The G2(MP2)-calculated PA(N-cyano) for (H₂N)₂CN–CN and (H₂N)₃PN–CN are larger than that of HCN by 186 and 250 kJ mol⁻¹, respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA02716K

Reference29 articles.

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3. A survey of Hammett substituent constants and resonance and field parameters

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