Lewis acid mediated allylation of vinyl diazonium ions by allylstannanes-Reference-Cited by-同舟云学术

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Lewis acid mediated allylation of vinyl diazonium ions by allylstannanes

Published:2024 Issue:21 Volume:22 Page:4274-4277
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Rose Benjamin J.¹,Brewer Matthias¹^ORCID

Affiliation:

1. 82 University Place, Department of Chemistry, University of Vermont, Burlington, VT 05401, USA

Abstract

The Lewis acid mediated allylation of β-hydroxy-α-diazo carbonyls gives β-allyl-α-diazo carbonyl products. The diazo functional group is retained over the course of the reaction giving functional group rich products.

Funder

Division of Chemistry

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00254G

Reference26 articles.

1. Organoboranes. 20. The facile allylboration of representative carbonyl compounds with B-allyl derivatives of 9-borabicyclo[3.3.1]nonane

2. Brown Allylation: Application to the Synthesis of Natural Products

3. Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride

4. ALLYLSILANES AS SYNTHETIC INTERMEDIATES. II. SYNTHESES OF HOMOALLYL ETHERS FROM ALLYLSILANES AND ACETALS PROMOTED BY TITANIUM TETRACHLORIDE

5. The remarkable journey of catalysts from stoichiometric to catalytic quantity for allyltrimethylsilane inspired allylation of acetals, ketals, aldehydes and ketones

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