Efficient diffusion of superdense lithium via atomic channels for dendrite-free lithium–metal batteries

Author:

Zhou Shiyuan1ORCID,Chen Weixin1,Shi Jie2ORCID,Li Gen1,Pei Fei1,Liu Sangui1,Ye Weibin3,Xiao Liangping1,Wang Ming-Sheng3ORCID,Wang Dan2ORCID,Qiao Yu14ORCID,Huang Ling1ORCID,Xu Gui-Liang5ORCID,Liao Hong-Gang14ORCID,Chen Jian-Feng2,Amine Khalil567ORCID,Sun Shi-Gang1ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

2. State Key Laboratory of Organic Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, P. R. China

3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, P. R. China

4. Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen 361005, P. R. China

5. Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA

6. Materials Science and Engineering, Stanford University, Stanford, CA, USA

7. Institute for Research & Medical Consultations, Imam Abdulrahman Bin Faisal University (IAU), Dammam, Saudi Arabia

Abstract

A novel concept of atomic channels within bulk graphite is proposed for the fast diffusion of multi-layered close-packed Li. The feasibility of bulk-diffusion of superdense Li have been verified in the dendrite-free Li metal batteries.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Argonne National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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