Mechanism of ammonia synthesis on Fe<sub>3</sub>Mo<sub>3</sub>N-Reference-Cited by-同舟云学术

Mechanism of ammonia synthesis on Fe₃Mo₃N

Published:2023 Issue: Volume: Page:
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Higham Michael D.¹²^ORCID,Zeinalipour-Yazdi Constantinos D.³^ORCID,Hargreaves Justin S. J.⁴,Catlow C. Richard A.¹²⁵^ORCID

Affiliation:

1. University College London, Department of Chemistry, Kathleen Lonsdale Building, Gower Place, London, WC1E 6BT, UK

2. Research Complex at Harwell, Rutherford Appleton Laboratory, Harwell, Oxon, OX11 0FA, UK

3. University of East London, University Way, London, E16 2RD, UK

4. University of Glasgow, School of Chemistry, Glasgow, G12 8QQ, UK

5. School of Chemistry, Cardiff University, Park Place, Cardiff, CF10 1AT, UK

Abstract

The novel Eley–Rideal–Mars–van-Krevelen mechanism for ammonia synthesis on Fe3Mo3N relies on the presence of surface lattice N vacancies and proceeds through the intermediate.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D2FD00148A

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