The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin(<scp>ii</scp>)-based oxalates-Reference-Cited by-同舟云学术

The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin(ii)-based oxalates

Published:2023 Issue:19 Volume:10 Page:5602-5610
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Ren Liying¹,Cheng Linhong¹,Zhou Xiaoyan¹,Ren Jinxuan¹,Cao Liling¹^ORCID,Huang Ling¹^ORCID,Dong Xuehua¹,Zhou Yuqiao²^ORCID,Gao Daojiang¹,Zou Guohong²^ORCID

Affiliation:

1. College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, P. R. China

2. College of Chemistry, Sichuan University, Chengdu 610065, P. R. china

Abstract

Through rational molecular engineering, a crystal structure is transformed from a 0D cluster of K2Sn(C2O4)2·H2O to a 1D chain of (K2Sn2(C2O4)2F2·H2O), and the corresponding birefringence increases dramatically from 0.103@546 nm to 0.301@546 nm.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Natural Science Foundation of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI01213A

Reference57 articles.

1. Designing an Excellent Deep-Ultraviolet Birefringent Material for Light Polarization