Resolving old problems with layered polytungstates related to hexagonal tungsten bronze: phase formation, structures, crystal chemistry and some properties-Reference-Cited by-同舟云学术

Resolving old problems with layered polytungstates related to hexagonal tungsten bronze: phase formation, structures, crystal chemistry and some properties

Published:2023 Issue:9 Volume:52 Page:2770-2785
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Solodovnikov Sergey F.¹^ORCID,Meshalkin Arkadiy B.²,Sukhikh Aleksandr S.¹^ORCID,Solodovnikova Zoya A.¹^ORCID,Zolotova Evgeniya S.¹,Yudin Vasiliy N.¹^ORCID,Kadyrova Yuliya M.³^ORCID,Khaikina Elena G.³^ORCID,Mateyshina Yuliya G.⁴,Uvarov Nikolai F.⁴^ORCID,Pugachev Aleksey M.⁵,Kovtunets Evgeniy V.³^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Acad. Lavrentyev Ave. 3, Novosibirsk 630090, Russia

2. Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, Acad. Lavrentyev Ave. 1, Novosibirsk 630090, Russia

3. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Sakh'yanova St. 6, Ulan-Ude, 670047, Buryat Republic, Russia

4. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Kutateladze St. 18, Novosibirsk 630128, Russia

5. Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, Acad. Koptyug Ave. 1, Novosibirsk 630090, Russia

Abstract

A 60-year-old mystery solved: the average structures of alkali polytungstates A4W11O35 and A2W7O22 (A = K, Rb, Cs) related to hexagonal tungsten bronze were determined.

Funder

Russian Foundation for Basic Research

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03895A

Reference95 articles.

1. Beitrag zur Kenntnis der Molybdate und Wolframate. Die bin�ren Systeme: Li3MoO4?MoO3, Na2MoO4?MoO3, K3MoO4?MoO3, Li2WO4?WO3, Na2WO4?WO3, K2WO4?WO3, Li2MoO4?Na2MoO4, Li2WO4?Na2WO4, Li2MoO4?K2MoO4

2. X-ray diffraction studies of potassium polytungstates with high WO3 content

3. The crystal structure of K2W4O13

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