Structural and silver/vanadium ratio effects on silver vanadium phosphorous oxide solution formation kinetics: Impact on battery electrochemistry-Reference-Cited by-同舟云学术

Structural and silver/vanadium ratio effects on silver vanadium phosphorous oxide solution formation kinetics: Impact on battery electrochemistry

Published:2015 Issue:3 Volume:17 Page:2034-2042
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bock David C.¹²³⁴,Takeuchi Kenneth J.¹²³⁴⁵,Marschilok Amy C.¹²³⁴⁵,Takeuchi Esther S.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Stony Brook University

3. Stony Brook

4. USA

5. Department of Materials Science and Engineering

Abstract

This study contains the first kinetic analyses of silver and vanadium solution formation from Ag_0.48VOPO₄·1.9H₂O and Ag₂VP₂O₈, in a non-aqueous battery electrolyte. The results presented here provide a framework for the quantitative and kinetic analyses of the dissolution of cathode materials which will aid the broader community in more fully understanding this battery failure mechanism.

Funder

National Institutes of Health

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04819A

Reference54 articles.

1. Batteries used to power implantable biomedical devices

2. Cobalt dissolution in LiCoO2-based non-aqueous rechargeable batteries