Spectroscopic characterization of neptunium(vi), plutonium(vi), americium(vi) and neptunium(v) encapsulated in uranyl nitrate hexahydrate-Reference-Cited by-同舟云学术

Spectroscopic characterization of neptunium(vi), plutonium(vi), americium(vi) and neptunium(v) encapsulated in uranyl nitrate hexahydrate

Published:2021 Issue:23 Volume:23 Page:13228-13241
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yu Xiaojuan¹²³^ORCID,Einkauf Jeffrey D.⁴⁵³^ORCID,Bryantsev Vyacheslav S.⁴⁵³^ORCID,Cheshire Michael C.⁴⁵³^ORCID,Reinhart Benjamin J.⁶⁷³^ORCID,Autschbach Jochen¹²³^ORCID,Burns Jonathan D.⁸⁹³^ORCID

Affiliation:

1. Department of Chemistry, University at Buffalo, State University of New York

2. Buffalo

3. USA

4. Chemical Sciences Division, Oak Ridge National Laboratory

5. Oak Ridge

6. X-Ray Sciences Division, Argonne National Laboratory

7. Lemont

8. Nuclear Engineering and Science Center, Texas A&M University

9. College Station

Abstract

The solid-state electronic structure of oxidized actinides was probed by co-crystallization of Np(vi), Pu(vi), Am(vi), and Np(v) with UO₂(NO₃)₂·6H₂O. XAS measurements and the solid-state absorption spectra were coupled with theoretical calculations.

Funder

Nuclear Energy University Programs

Basic Energy Sciences

Oak Ridge National Laboratory

Texas A and M University

University at Buffalo

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01047F