Understanding the anomalous behavior of Vegard's law in Ce1−xMxO2 (M = Sn and Ti; 0 < x ≤ 0.5) solid solutions-Reference-Cited by-同舟云学术

Understanding the anomalous behavior of Vegard's law in Ce1−xMxO2 (M = Sn and Ti; 0 < x ≤ 0.5) solid solutions

Published:2016 Issue:20 Volume:18 Page:13974-13983
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Baidya Tinku¹²³⁴⁵,Bera Parthasarathi⁶⁷⁸⁴,Kröcher Oliver⁵⁹¹⁰¹¹¹²,Safonova Olga⁵⁹¹⁰,Abdala Paula M.¹³¹⁴¹⁵¹⁶,Gerke Birgit¹⁷¹⁸¹⁹²⁰,Pöttgen Rainer¹⁷¹⁸¹⁹²⁰,Priolkar Kaustubh R.²¹²²²³²⁴⁴,Mandal Tapas Kumar²⁵²⁶²⁷⁴

Affiliation:

1. Solid State and Structural Chemistry Unit

2. Indian Institute of Science

3. Bangalore 560012

4. India

5. Paul Scherrer Institut

6. Surface Engineering Division

7. CSIR − National Aerospace Laboratories

8. Bangalore 560017

9. 5253 Villigen

10. Switzerland

11. Ecole Polytechnique Fédérale de Lausanne (EPFL)

12. 1015 Lausanne

13. SNBL

14. European Synchrotron Radiation Facility

15. 38043 Grenoble

16. France

17. Institut für Anorganische und Analytische Chemie

18. Universität Münster

19. 48149 Münster

20. Germany

21. Department of Physics

22. Goa University

23. Taleigao Plateau

24. Goa 403206

25. Department of Chemistry and Centre of Nanotechnology

26. Indian Institute of Technology Roorkee

27. Roorkee 247667

Abstract

A lattice parameter vs. ‘x’ curve in Ce_1−xSn_xO₂ (x = 0.0–0.5) solid solutions is deviated from systematic linearity unlike in Ce_1−xZr_xO₂ due to higher electronegativity of Sn.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP01525E

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