Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts-Reference-Cited by-同舟云学术

Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts

Published:2017 Issue:38 Volume:46 Page:12780-12784
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bartalucci Niccolò¹²³⁴,Bortoluzzi Marco⁵⁶⁷⁴,Funaioli Tiziana¹²³⁴,Marchetti Fabio¹²³⁴^ORCID,Pampaloni Guido¹²³⁴,Zacchini Stefano⁸⁹¹⁰⁴^ORCID

Affiliation:

1. University of Pisa

2. Dipartimento di Chimica e Chimica Industriale

3. I-56124 Pisa

4. Italy

5. University Ca’ Foscari Venezia

6. Dipartimento di Scienze Molecolari e Nanosistemi

7. I-30170 Mestre

8. University of Bologna

9. Dipartimento di Chimica Industriale “Toso Montanari”

10. I-40136 Bologna

Abstract

BREAKING THE RULE! N-(2,6-diisopropylphenyl) α-diimines, known to be robust ligands in coordination chemistry, convert into quinoxalinium cations by reaction with WCl₆ in mild conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03226A

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