Light-enabled metal-free pinacol coupling by hydrazine

Author:

Qiu Zihang12345ORCID,Pham Hanh D. M.12345,Li Jianbin12345ORCID,Li Chen-Chen12345ORCID,Castillo-Pazos Durbis J.12345ORCID,Khaliullin Rustam Z.12345ORCID,Li Chao-Jun12345ORCID

Affiliation:

1. Department of Chemistry

2. FQRNT Centre for Green Chemistry and Catalysis

3. McGill University

4. Montreal

5. Canada

Abstract

A light-driven pinacol coupling protocol without any metals, but with N2H4 as a clean non-metallic hydrogen-atom-transfer (HAT) reductant was described.

Funder

McGill University

Natural Sciences and Engineering Research Council of Canada

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference44 articles.

1. The economies of synthesis

2. T. Hirao , Catalytic Reductive Coupling of Carbonyl Compounds – The Pinacol Coupling Reaction in Metal Catalyzed Reductive C–C Bond Formation , ed. M. J. Krische , Springer Berlin Heidelberg , Berlin, Heidelberg , 2007 , ch.120, pp. 53–75

3. “New” Reagents for the“Old” Pinacol Coupling Reaction

4. Zn-AlCl3 · 6H2O-Mediated Reaction in Aqueous Media: Pinacol Coupling Reaction

5. Zinc-Mediated Efficient and Selective Reduction of Carbonyl Compounds

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