UV-induced radical formation and isomerization of 4-methoxyindole and 5-methoxyindole-Reference-Cited by-同舟云学术

UV-induced radical formation and isomerization of 4-methoxyindole and 5-methoxyindole

Published:2020 Issue:40 Volume:22 Page:22943-22955
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lopes Jesus A. J.¹²³⁴⁵^ORCID,Rosado Mário T. S.¹²³⁴⁵^ORCID,Fausto R.¹²³⁴⁵^ORCID,Reva I.¹²³⁴⁵^ORCID

Affiliation:

1. University of Coimbra

2. CQC

3. Department of Chemistry

4. Coimbra

5. Portugal

Abstract

UV-excitation of matrix-isolated methoxyindoles induces the N–H bond cleavage resulting in indolyl radicals. These, in turn, recombine with the released H atom to form 3H-tautomers.

Funder

Fundação para a Ciência e a Tecnologia

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP04354K

Reference82 articles.

1. Indole synthesis – something old, something new

2. Biomedical Importance of Indoles

3. 1-(2-Alkanamidoethyl)-6-methoxyindole Derivatives: A New Class of Potent Indole Melatonin Analogues

4. Assessment of the pharmacological properties of 5-methoxyindole derivatives at 5-HT4 receptors

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