Catalytic cascade synthesis of cyanohydrin esters via water/O2-induced cyanide transfer from K3Fe(CN)6-Reference-Cited by-同舟云学术

Catalytic cascade synthesis of cyanohydrin esters via water/O₂-induced cyanide transfer from K₃Fe(CN)₆

Published:2023 Issue:77 Volume:59 Page:11544-11547
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Singh Anupam Kumar¹²,Chauhan Shivani Singh¹²,Bhadra Sukalyan¹²^ORCID

Affiliation:

1. Inorganic Materials and Catalysis Division, CSIR-Central Salt and Marine Chemicals Research Institute, G.B. Marg, Bhavnagar, Gujarat 364002, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

Abstract

The Cu-catalyzed α-oxygenation of aryl benzyl ketones has been integrated with a unique water/O2-induced cyanide release process from K3Fe(CN)6 and a benzil-cyanide reaction to give a new entry to cyanohydrin esters.

Funder

Science and Engineering Research Board

Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02743K

Reference47 articles.

1. C.Young , L.Tidwell and C.Anderson , Cyanide: Social, Industrial, and Economic Aspects; Minerals, Metals, and Materials Society , Warrendale , 2001

2. Strecker reactions with hexacyanoferrates as non-toxic cyanide sources

3. Mechanochemical Activation of Iron Cyano Complexes: A Prebiotic Impact Scenario for the Synthesis of α-Amino Acid Derivatives

4. α-Cyanation of Aromatic Tertiary Amines using Ferricyanide as a Non-Toxic Cyanide Source

5. Synthesis of Unsymmetrical Diarylfumaronitriles via Tandem Michael Addition and Oxidation under K₃Fe(CN)₆/O₂ System

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Efficient Synthesis of Cyanohydrin Esters: P(NMe₂)₃ Mediated Direct Deoxygenation of Acyl Cyanides with Carboxylic Acids;The Journal of Organic Chemistry;2024-08-08

2. Cobalt Catalyzed α-Hydroxylation of Arylacetic Acid Equivalents with Dioxygen;The Journal of Organic Chemistry;2024-06-15