Chemodivergent phosphonylation of diazocarboxylates: light-on <i>vs</i>. light-off reactions-Reference-Cited by-同舟云学术

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Chemodivergent phosphonylation of diazocarboxylates: light-on vs. light-off reactions

Published:2024 Issue:25 Volume:22 Page:5224-5228
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Pathak Jalaj Kumar¹²,Kant Ruchir³,Rastogi Namrata¹²^ORCID

Affiliation:

1. Medicinal & Process Chemistry Division, CSIR-Central Drug Research Institute, Lucknow-226031, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Biochemistry & Structural Biology Division, CSIR-Central Drug Research Institute, Lucknow-226031, India

Abstract

The reaction between a-diazocarboxylates and trialkylphosphites under thermal and photochemical conditions results into N–P and C–P bond formation, respectively. The diazo substrates act as electrophiles in the former case and as carbene precursors in the later case.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00573B

Reference43 articles.

1. Synthesis of Nucleoside Phosphate and Phosphonate Prodrugs

2. Selected organophosphorus compounds with biological activity. Applications in medicine

3. The Role of the Phosphorus Atom in Drug Design

4. The Role of Phosphorus in Crop Protection: Commercial and Experimental Weed Control Agents

5. C–P Natural Products as Next-Generation Herbicides: Chemistry and Biology of Glufosinate

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