Synthesis and elucidation of local structure in phase-controlled colloidal tin phosphide nanocrystals from aminophosphines

Author:

Paredes Ingrid J.1,Ebrahim Amani M.2,Yanagi Rito134,Plonka Anna M.2,Chen Shuzhen1,Xia Hanlu1,Lee Scott1,Khwaja Mersal1,Kannan Haripriya1,Singh Ajay5,Hwang Sooyeon6ORCID,Frenkel Anatoly I.27ORCID,Sahu Ayaskanta1ORCID

Affiliation:

1. Department of Chemical and Biomolecular Engineering, New York University Tandon School of Engineering, 6 Metrotech Center, Brooklyn, New York, 11201, USA

2. Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11794, USA

3. Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut, 06520, USA

4. Energy Sciences Institute, Yale University, 810 West Campus Drive, West Haven, Connecticut, 06516, USA

5. Center for Integrated Nanotechnologies, Material Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

6. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA

7. Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, USA

Abstract

Aminophosphines are a class of inexpensive, environmentally benign phosphorus precursors that have provided routes to various metal phosphides. In this work, we use the aminophosphine tris(diethyl)aminophosphine to synthesize tin phosphide nanocrystals.

Funder

U.S. Department of Energy

National Science Foundation

Office of Science

Workforce Development for Teachers and Scientists

Oak Ridge Institute for Science and Education

Brookhaven National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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