Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structure-Reference-Cited by-同舟云学术

Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structure

Published:2017 Issue:22 Volume:46 Page:7261-7266
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Qiu Chaoqun¹²³⁴⁵,He Zhangzhen¹²³⁴⁵^ORCID,Cui Meiyan¹²³⁴⁵,Chen Sihuai¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. Fujian Institute of Research on the Structure of Matter

3. Chinese Academy of Sciences

4. Fuzhou

5. China

Abstract

Fluorophosphates, BaMPO₄F (M = Cu, Co), with a tunnel structure show different magnetic behaviors, in which BaCuPO₄F exhibits a paramagnetic behavior down to 2 K, while BaCoPO₄F undergoes long-range antiferromagnetic ordering at low temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01408B

Reference25 articles.

1. A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries

2. Tavorite Lithium Iron Fluorophosphate Cathode Materials: Phase Transition and Electrochemistry of LiFePO[sub 4]F–Li[sub 2]FePO[sub 4]F

3. A comparative study on Na2MnPO4F and Li2MnPO4F for rechargeable battery cathodes

4. High Voltage Performances of Li[sub 2]NiPO[sub 4]F Cathode with Dinitrile-Based Electrolytes

5. Fluoride phosphate Li2CoPO4F as a high-voltage cathode in Li-ion batteries

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