Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2-Reference-Cited by-同舟云学术

Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2

Published:2016 Issue:73 Volume:52 Page:10992-10995
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kather Ralf¹²³⁴,Rychagova Elena⁵⁶⁷,Sanz Camacho Paula⁸⁹¹⁰¹¹,Ashbrook Sharon E.⁸⁹¹⁰¹¹,Woollins J. Derek⁸⁹¹⁰¹¹,Robben Lars¹²³⁴,Lork Enno¹²³⁴,Ketkov Sergey⁵⁶⁷¹²⁶,Beckmann Jens¹²³⁴

Affiliation:

1. Institut of Inorganic Chemistry and Crystallography

2. Bremen University

3. 28359 Bremen

4. Germany

5. G. A. Razuvaev Institute of Organometallic Chemistry RAS

6. 603950 Nizhny Novgorod

7. Russian Federation

8. EaStChem. School of Chemistry

9. University of St. Andrews

10. Fife KY16 9ST

11. UK

12. N. I. Lobachevsky Nizhny Novgorod State University

Abstract

The strong acid (C₆F₅)₃BOPPh₂OH, was prepared in situ by the reaction of the rather weak Brønsted acid Ph₂PO₂H with the strong Lewis acid B(C₆F₅)₃.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC06102H

Reference42 articles.

1. Superacid Chemistry, ed. G. A. Olah, G. K. S. Prakash, A. Molnár and J. Sommer, John Wiley & Sons, Inc., Hoboken, New Jersey, 2nd edn, 2009

2. Equilibria in the B(C6F5)3–H2O system: synthesis and crystal structures of H2O·B(C6F5)3 and the anions [HOB(C6F5)3]− and [(F5C6)3B(μ-OH)B(C6F5)3]−

3. Aqua, Alcohol, and Acetonitrile Adducts of Tris(perfluorophenyl)borane: Evaluation of Brønsted Acidity and Ligand Lability with Experimental and Computational Methods

4. Silica-Grafted Borato Cocatalysts for Olefin Polymerization Modeled by Silsesquioxane−Borato Complexes

5. Dimethyl(2-methylphenyl)ammonium hydroxotris(pentafluorophenyl)borate

Cited by 24 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. On the Keto‐Enol‐Tautomerism of 2‐(1‐Hydroxyethylidene)malononitrile and Its Lewis Adduct Formation with B(C₆F₅)₃;European Journal of Organic Chemistry;2024-01-26

2. An investigation into the Brønsted acidity of the perfluorinated alkoxy silanes {(F₃C)₃CO}₃SiH and {(F₆C₅)₃CO}₂Si(Cl)H;Dalton Transactions;2023

3. A Lewis Acid Stabilized Ketenimine in an Unusual Variant of the Electrophilic Aromatic Substitution;Chemistry – A European Journal;2022-10-07

4. Protonolysis of the [B(Ar_F)₄]⁻ Anion Mediated by Nucleophile/Electrophile/Water Cooperativity in a Platinum–PMe₂OH Complex;Organometallics;2022-05-30

5. Perfluorinated Dialkoxysilanediols Resisting Self‐Condensation;European Journal of Inorganic Chemistry;2021-10-22