Synthesis of high molar mass poly(n-butyl acrylate) and poly(2-ethylhexyl acrylate) by SET-LRP in mixtures of fluorinated alcohols with DMSO
Author:
Affiliation:
1. Roy & Diana Vagelos Laboratories
2. Department of Chemistry
3. University of Pennsylvania
4. Philadelphia
5. USA
Abstract
SET-LRP of n-butyl acrylate (nBA) and 2-ethylhexyl acrylate (EHA) initiated with bis(2-bromopropionyl)ethane (BPE) to synthesize high molar mass poly(nBA) and poly(EHA) was carried out in binary mixtures of 2,2,2-trifluoroethanol (TFE) or 2,2,3,3-tetrafluoropropanol (TFP) with DMSO at 50 °C.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2014/PY/C3PY01008B
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