Consecutive reactions of small, free tantalum clusters with dioxygen controlled by relaxation dynamics
Author:
Affiliation:
1. Lehrstuhl für Physikalische Chemie
2. Chemistry Department & Catalysis Research Center
3. Technische Universität München
4. 85748 Garching
5. Germany
6. Lehrstuhl für Theoretische Chemie
Abstract
The reaction of small cationic tantalum clusters (Tan+, n = 4–8) with molecular oxygen is studied under multi-collision conditions in the gas phase, and the reaction kinetics are analyzed in order to elucidate underlying mechanisms.
Funder
European Research Council
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP07631A
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