Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts-Reference-Cited by-同舟云学术

Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts

Published:2022 Issue:12 Volume:51 Page:4634-4643
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Redman Holly J.¹,Huang Ping¹^ORCID,Haumann Michael²^ORCID,Cheah Mun Hon¹^ORCID,Berggren Gustav¹^ORCID

Affiliation:

1. Department of Chemistry – Ångström Laboratory, Uppsala University, Box 523, 75120 Uppsala, Sweden

2. Department of Physics, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany

Abstract

Mimicking the hydrogen-bonding interactions of the [FeFe]-hydrogenase active-site using Lewis acids transforms an otherwise unstable cyanide containing hydrogenase mimic into a proton reduction catalyst.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03896F

Reference69 articles.

1. Catalytic Turnover of [FeFe]-Hydrogenase Based on Single-Molecule Imaging

2. Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices

3. Current State of [FeFe]-Hydrogenase Research: Biodiversity and Spectroscopic Investigations

4. [FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

5. Hydrogenases

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