Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)-Reference-Cited by-同舟云学术

Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)

Published:2017 Issue:59 Volume:7 Page:37315-37323
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Keyes Lauren K.¹²³⁴,Todd Angela D. K.¹²³⁴,Giffin Nick A.¹²³⁴,Veinot Alex J.¹²³⁴^ORCID,Hendsbee Arthur D.¹²³⁴,Robertson Katherine N.¹²³⁴^ORCID,Geier Stephen J.⁵⁶⁷⁴,Masuda Jason D.¹²³⁴^ORCID

Affiliation:

1. The Department of Chemistry

2. Saint Mary's University

3. Halifax

4. Canada

5. Department of Chemistry

6. Mount Alison University

7. Sackville

Abstract

A bulky aluminum dihydride reacts with R–OH and organocarbonyls to give a variety of products; including OC insertion into the Al–H bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA06526D

Reference47 articles.

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2. Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

3. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

4. New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules

5. N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

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