Ammonia-modified Co(ii) sites in zeolites: spin and electron density redistribution through the CoII

Ammonia-modified Co(ii) sites in zeolites: spin and electron density redistribution through the CoII–NO bond

Published:2016 Issue:5 Volume:18 Page:3716-3729
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Stępniewski Adam¹²³,Radoń Mariusz⁴⁵⁶³,Góra-Marek Kinga⁴⁵⁶³,Broclawik Ewa¹²³

Affiliation:

1. Jerzy Haber Institute of Catalysis PAS

2. 30-239 Krakow

3. Poland

4. Faculty of Chemistry

5. Jagiellonian University

6. 30-060 Krakow

Abstract

Both considerable share of the Co^III–NO⁻ resonance structure and large π*-backdonation (evidenced by electron density transfer channels) rationalize the huge activation of the NO ligand in [Co(ii)(NH₃)_n]–NO adducts.

Funder

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP07452E

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