Chiral organometallic NADH mimics: stereoselective reduction of ethyl benzoylformate utilising the homochiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] at C-3 and a chiral β-hydroxy-carboxamide derived from valinol at C-5-Reference-Cited by-同舟云学术

Chiral organometallic NADH mimics: stereoselective reduction of ethyl benzoylformate utilising the homochiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] at C-3 and a chiral β-hydroxy-carboxamide derived from valinol at C-5

Published:1990 Issue:24 Volume:0 Page:1759-1762
ISSN:0022-4936
Container-title:J. Chem. Soc., Chem. Commun.
language:en
Short-container-title:J. Chem. Soc., Chem. Commun.

Author:

Burgess Vicky A.,Davies Stephen G.,Skerlj Renato T.

Publisher

Royal Society of Chemistry (RSC)

Subject

Molecular Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/1990/C3/C39900001759

Reference17 articles.

1. A. Ohno and S.Ushida, Mechanistic Models of Asymmetric Reductions in Lecture notes in Bioorganic Chemistry, Springer Verlag, Heidelberg, 1986;

2. Model studies with nicotinamide derivatives

3. Reduction by a model of NAD(P)H. Effect of metal ion and stereochemistry on the reduction of .alpha.-keto esters by 1,4-dihydronicotinamide derivatives

4. Reduction by a model of NAD(P)H. 25. A chiral model which induces high asymmetry

5. Reductions with Chiral Dihydropyridine Reagents

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