Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium

Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond

Published:2016 Issue:9 Volume:7 Page:5857-5866
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rosenzweig Michael W.¹²³⁴⁵,Scheurer Andreas¹²³⁴⁵,Lamsfus Carlos A.⁶⁷⁸⁹¹⁰,Heinemann Frank W.¹²³⁴⁵,Maron Laurent⁶⁷⁸⁹¹⁰,Andrez Julie¹¹¹²¹³¹⁴,Mazzanti Marinella¹¹¹²¹³¹⁴,Meyer Karsten¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Pharmacy

2. Inorganic Chemistry

3. Friedrich-Alexander University Erlangen-Nürnberg

4. 91058 Erlangen

5. Germany

6. LPCNO

7. Université de Toulouse

8. INSA Toulouse

9. 31077 Toulouse

10. France

11. Institut des Sciences et Ingénierie Chimiques

12. Ecole Polytechnique Fédérale de Lausanne (EPFL)

13. 1015 Lausanne

14. Switzerland

Abstract

We report the synthesis and characterization of terminal uranium(iv) hydrosulfido and sulfido complexes, supported by the hexadentate, tacn-based ligand (^Ad,MeArO)₃tacn³⁻.

Funder

Bundesministerium für Bildung und Forschung

Agence Nationale de la Recherche

Deutsche Forschungsgemeinschaft

Friedrich-Alexander-Universität Erlangen-Nürnberg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00677A

Reference74 articles.