Spectroscopic characterization of carbon monoxide activation by neutral chromium carbides-Reference-Cited by-同舟云学术

Spectroscopic characterization of carbon monoxide activation by neutral chromium carbides

Published:2024 Issue:7 Volume:26 Page:5962-5968
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Tiantong¹²,Zhang Zhaoyan¹²,Jiang Shuai¹²,Yan Wenhui¹²,Li Shangdong¹²,Zhuang Jianxing¹²,Xie Hua¹^ORCID,Li Gang¹^ORCID,Jiang Ling¹³^ORCID

Affiliation:

1. State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. Hefei National Laboratory, Hefei 230088, China

Abstract

A size-specific infrared-vacuum ultraviolet spectroscopic study of the reactions between carbon monoxide with chromium carbides reveals a semi-bridging CO, which is highly activated through the Cr–C–C three-center two-electron interaction.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Dalian Institute of Chemical Physics, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00011K

Reference50 articles.

1. Advances in the Development of Novel Cobalt Fischer−Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels

2. Molecular Views on Fischer–Tropsch Synthesis

3. Applied Hydroformylation

4. Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis

5. Recent advances in the routes and catalysts for ethanol synthesis from syngas

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