Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling
Author:
Affiliation:
1. Institut des Biomolécules Max Mousseron (IBMM)
2. UMR 5247
3. Université de Montpellier
4. CNRS
5. ENSCM
Abstract
A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03564G
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5. The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P 4 (N t Bu) 6 : Enabled by Mechanochemistry
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