Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

Author:

Beillard Audrey12345,Bantreil Xavier12345ORCID,Métro Thomas-Xavier12345ORCID,Martinez Jean12345,Lamaty Frédéric12345

Affiliation:

1. Institut des Biomolécules Max Mousseron (IBMM)

2. UMR 5247

3. Université de Montpellier

4. CNRS

5. ENSCM

Abstract

A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference42 articles.

1. Mechanochemical organic synthesis

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3. Mechanochemistry: opportunities for new and cleaner synthesis

4. T.-X. Métro , E.Colacino, J.Martinez and F.Lamaty, in Ball Milling Towards Green Synthesis: Applications, Projects, Challenges, ed. A. Stolle, B. Ranu, The Royal Society of Chemistry, 2015, p. 114

5. The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P 4 (N t Bu) 6 : Enabled by Mechanochemistry

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