Hydride, chloride, and bromide show similar electronic effects in the Au9(PPh3)83+ nanocluster-Reference-Cited by-同舟云学术

Hydride, chloride, and bromide show similar electronic effects in the Au9(PPh3)83+ nanocluster

Published:2020 Issue:8 Volume:56 Page:1283-1285
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cirri Anthony¹²³^ORCID,Hernández Hanna Morales¹²³,Johnson Christopher J.¹²³^ORCID

Affiliation:

1. Stony Brook University

2. Stony Brook

3. USA

Abstract

Hydride and halide ligands in gold nanoclusters exhibit an unexpected similar electronic relationship, suggesting an underlying chemical linkage between them.

Funder

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08009K

Reference20 articles.

1. Atomically Precise Metal Nanoclusters for Catalysis

2. Hydride-Doped Gold Superatom (Au9H)2+: Synthesis, Structure, and Transformation

3. Synthesis of Trimetallic (HPd@M2Au8)3+ Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au8)2+

4. Efficient and Selective Conversion of Phosphine-Protected (MAu8)2+ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu12)6+ or Alkynyl-Protected (MAu12)4+ Superatoms via Hydride Doping

5. Formation and Characterisation of the Silver Hydride Nanocluster Cation [Ag3H2((Ph2P)2CH2)]+and Its Release of Hydrogen

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