On the alcoholysis of alkyl-aluminum(iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl-Reference-Cited by-同舟云学术

On the alcoholysis of alkyl-aluminum(iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl

Published:2018 Issue:31 Volume:47 Page:10429-10433
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dardun Vincent¹²³⁴⁵^ORCID,Escomel Léon¹²³⁴⁵^ORCID,Jeanneau Erwann¹⁴⁶⁷⁸,Camp Clément¹²³⁴⁵^ORCID

Affiliation:

1. Université de Lyon

2. Institut de Chimie de Lyon

3. C2P2 UMR 5265 CNRS

4. Université Lyon 1

5. ESCPE Lyon

6. Centre de Diffractométrie Henri Longchambon

7. Site CLEA-Bâtiment ISA

8. 69100 Villeurbanne

Abstract

Alkyl-aluminum(iii) derivatives supported by a bifunctional alkoxy-NHC ligand display unusual reactivity at the carbene, yielding imidazolium-aluminate zwitterions.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01498A

Reference55 articles.

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