Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P− into a P−P bond-Reference-Cited by-同舟云学术

Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P− into a P−P bond

Published:2019 Issue:22 Volume:55 Page:3187-3190
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Coburger Peter¹²³^ORCID,Grützmacher Hansjörg⁴⁵⁶⁷⁸^ORCID,Hey-Hawkins Evamarie¹²³^ORCID

Affiliation:

1. Leipzig University, Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry

2. D-04103 Leipzig

3. Germany

4. ETH Zurich, Lab. für Anorganische Chemie

5. 8093 Zürich

6. Switzerland

7. Lehn Institute of Functional Materials (LIFM), School of Chemistry, Sun Yat-sen University

8. Guangzhou 510275

Abstract

Insertion of a P⁻ anion into a P–P bond yielding the first carborane-substituted 1,2,3-triphospholanide 1 was achieved by treating a carborane-substitued 1,2-diphosphetane with sodium phosphaethynolate.

Funder

Studienstiftung des Deutschen Volkes

Eidgenössische Technische Hochschule Zürich

Sun Yat-sen University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00205G

Reference33 articles.

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4. P–N/P–P Bond Metathesis for the Synthesis of Complex Polyphosphanes

5. The new diphosphanylphosphido complexes of tungsten(vi) and molybdenum(vi). Their synthesis, structures and properties

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