Theoretical investigations of the reactivity of neutral molecules that feature an MM (M = B, Al, Ga, In, and Tl) double bond
Author:
Affiliation:
1. Department of Applied Chemistry, National Chiayi University
2. Chiayi 60004
3. Taiwan
4. Department of Medicinal and Applied Chemistry, Kaohsiung Medical University
5. Kaohsiung 80708
Abstract
The geometry, the electronic structure and the reactivity of compounds that feature a central MM (M = group 13 element) double bond with two sterically bulky ligands (L1 = tBu2MeSi and L2 = NHCiPr), L1L2MML1L2 (Rea-MM) are studied at the B3LYP-D3(BJ)/def2-SVP level of theory.
Funder
Ministry of Science and Technology, Taiwan
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01294J
Reference69 articles.
1. Boron-Phosphorus Compounds and Multiple Bonding
2. Multiple bonding, π-bonding contributions and aromatic character in isoelectronic boron-phosphorus, boron-arsenic, aluminum-nitrogen and zinc-sulfur compounds
3. Recent Advances in Phosphinoborane Chemistry
4. π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
5. Gallanes, Gallenes, Cyclogallenes, and Gallynes: Organometallic Chemistry about the Gallium−Gallium Bond
Cited by 9 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Theoretical Investigation on Dialumenes toward Dihydrogen Activation: Mechanism and Ligand Effect;The Journal of Physical Chemistry A;2024-04-18
2. The Impact of Substitution of Diphenyl Dialumene on the Molecular Structure and Energetic Properties;Indonesian Journal of Chemistry;2024-04-01
3. π-Hole Triel Bonds between TrPhX2 (Tr = B, Al, Ga; X = F, Cl, Br, CH3, OH) and (BH)2(NHC)2 (NHC = Nitrogen-Heterocyclic Carbene);Crystals;2023-05-26
4. Insights into the Reactivity of the Ring-Opening Reaction of Tetrahydrofuran by Intramolecular Group-13/P- and Al/Group-15-Based Frustrated Lewis Pairs;ACS Omega;2023-01-31
5. Origin of interfacial charges of Al2O3/Si and Al2O3/GaN heterogeneous heterostructures;Applied Surface Science;2023-01
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3