Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights-Reference-Cited by-同舟云学术

Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights

Published:2019 Issue:43 Volume:10 Page:10072-10078
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gevorgyan Ashot¹²³^ORCID,Obst Marc F.⁴¹²³^ORCID,Guttormsen Yngve¹²³,Maseras Feliu⁵⁶^ORCID,Hopmann Kathrin H.⁴¹²³^ORCID,Bayer Annette¹²³^ORCID

Affiliation:

1. Department of Chemistry

2. UiT The Arctic University of Norway

3. Norway

4. Hylleraas Centre for Quantum Molecular Sciences

5. Institute of Chemical Research of Catalonia (ICIQ)

6. Spain

Abstract

A caesium fluoride-mediated regioselective hydrocarboxylation of alkenes and allenes is described. Computational studies reveal that the stability of an organocaesium intermediate accounts for the observed reactivity.

Funder

Norges Forskningsråd

NordForsk

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02467K

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