Insertion of CO<sub>2</sub>and CS<sub>2</sub>into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer-Reference-Cited by-同舟云学术

Insertion of CO₂and CS₂into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer

Published:2023 Issue:19 Volume:14 Page:5214-5219
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Oberdorf Kai¹,Hanft Anna¹,Xie Xiulan¹,Bickelhaupt F. Matthias²³⁴^ORCID,Poater Jordi⁵^ORCID,Lichtenberg Crispin¹^ORCID

Affiliation:

1. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35043 Marburg, Germany

2. Theoretical Chemistry, Department of Chemistry and Pharmaceutical Sciences, Vrije Universiteit Amsterdam, The Netherlands

3. Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands

4. Department of Chemical Sciences, University of Johannesburg, Auckland Park, Johannesburg 2006, South Africa

5. Departament de Química Inorgànica i Orgànica, IQTCUB, Universitat de Barcelona, ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

CO2and CS2cleanly insert into Bi–N bonds of cationic bismuth amides. The insertion products are metastable and undergo either CO2elimination along with CH activation or light-induced bismuth(i) triflate elimination along with C–S bond formation.

Funder

Fonds der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

H2020 European Research Council

Ministerio de Ciencia e Innovación

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01635H

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