Atomically manipulated proton transfer energizes water oxidation on silicon carbide photoanodes-Reference-Cited by-同舟云学术

Atomically manipulated proton transfer energizes water oxidation on silicon carbide photoanodes

Published:2018 Issue:47 Volume:6 Page:24358-24366
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Li Hao¹²³⁴,Shang Huan⁵⁶⁷⁸⁹,Shi Yuchen¹²³⁴,Yakimova Rositsa¹²³⁴,Syväjärvi Mikael¹²³⁴,Zhang Lizhi⁵⁶⁷⁸⁹^ORCID,Sun Jianwu¹²³⁴^ORCID

Affiliation:

1. Department of Physics, Chemistry and Biology

2. Linköping University

3. 58183 Linköping

4. Sweden

5. Key Laboratory of Pesticide & Chemical Biology of Ministry of Education

6. Institute of Applied & Environmental Chemistry

7. College of Chemistry

8. Central China Normal University

9. Wuhan 430079

Abstract

Preferential exposure of Si-face of SiC will mechanistically shift the rate limiting step of water oxidation from sluggish proton-coupled electron transfer on C-face to a more energy-favorable electron transfer.

Funder

Svenska Forskningsrådet Formas

Swedish Foundation for International Cooperation in Research and Higher Education

Vetenskapsrådet

Stiftelsen Åforsk

Stiftelsen Olle Engkvist Byggmästare

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/TA/C8TA08631A

Reference51 articles.

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2. Photocatalytic Water Splitting: Quantitative Approaches toward Photocatalyst by Design

3. Photoelectrocatalytic Water Splitting: Significance of Cocatalysts, Electrolyte, and Interfaces

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5. Activation of Water in Titanium Dioxide Photocatalysis by Formation of Surface Hydrogen Bonds: An In Situ IR Spectroscopy Study

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