Synthesis and catalytic activity of heterobimetallic Au/M (M = Rh<sup>III</sup>, Ir<sup>III</sup>) complexes with ditopic mono- and triphosphane ligands-Reference-Cited by-同舟云学术

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Synthesis and catalytic activity of heterobimetallic Au/M (M = Rh^III, Ir^III) complexes with ditopic mono- and triphosphane ligands

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Predarska Ivana¹^ORCID,Körber Wieland¹,Lönnecke Peter¹^ORCID,Gelman Dmitri²^ORCID,Hey-Hawkins Evamarie¹^ORCID

Affiliation:

1. Leipzig University, Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Johannisallee 29, 04103 Leipzig, Germany

2. The Hebrew University, Institute of Chemistry, Edmond Safra Campus, 9190401 Jerusalem, Israel

Abstract

Universal ligand frameworks for designing heterobimetallic catalysts are described. Au/M (M = RhIII, IrIII) complexes were prepared with a ditopic mono- or triphosphane ligand. Gold(i) is only catalytically active when coordinated by a monophosphane.

Funder

German-Israeli Foundation for Scientific Research and Development

Graduate School BuildMoNa

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01247J

Reference49 articles.

1. Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings

2. Asymmetric Two-Center Catalysis—Learning from Nature

3. Structure and mechanism of copper, zinc superoxide dismutase

4. Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase

5. Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase

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