A designed and potentially decadentate ligand for use in lanthanide(iii) catalysed biomass transformations: targeting diastereoselective trans-4,5-diaminocyclopentenone derivatives

Author:

Peewasan Krisana1234ORCID,Merkel Marcel P.5674ORCID,Fuhr Olaf56748ORCID,Powell Annie K.12345ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Karlsruhe Institute of Technology

3. 76131 Karlsruhe

4. Germany

5. Institute of Nanotechnology

6. Karlsruhe Institute of Technology Campus North

7. 76344 Eggenstein-Leopoldshafen Karlsruhe

8. Karlsruhe Nano Micro Facility Karlsruhe Institute of Technology

Abstract

The catalysis of furfural to diastereoselective trans-4,5-diaminocyclopentenone building blocks for natural product synthesis for a wide range of amines was achieved under mild aerobic conditions.

Funder

Deutsche Forschungsgemeinschaft

Helmholtz-Gemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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